Product ID:ENVI-RO-TECH MINUS 96 FREEZER, 1696
MSDS Date:02/22/1992
FSC:6850
NIIN:01-336-2882
MSDS Number: BRMCB

TECH SPRAY INC

88 HUGHES ST
AMARILLO, TX 79105-0949
US

Emergency Phone: 806-372-8523;800-858-4043

Info Phone: 806-372-8523;800-858-4043

Preparer: B. RIFFEL

Cage: DO677

TECH SPRAY INC

949 AMARILLO, TX 79105-0949 US

Telephone: 806-372-8523

Cage: DO677

METHANE, CHLORODIFLUORO-; (CHLORODIFLUOROMETHANE)

CAS: 75-45-6

RTECS: PA6390000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

OF OVEREXP TO PROD.

RTECS: 9999999ZZ

VITON, POLYVINYL ALCOHOL.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAJOR POTNTL RTE OF
EXPOS. MINIMAL EFTS OBSERVED BELOW 1000PPM. DIZZ, DROW, & THROAT
IRRIT POSS @ LEVELS ABOVE 1,000 PPM. UNCON & DEATH @ LEVELS ABOVE
10,000PPM. BLOOD PRESS DEPRESS, CAR DIAC SENSIT, & VENTRICULAR
ARRHYTHMIA CAN RSLT FROM EXPOS TO NEAR-ANESTH LEVELS. EYES: LIQ CAN
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SLIGHT, TEMP IRRIT W/SLIGHT TEMP
CORNEAL INJURY. VAPS CAN IRRITATE EYES. SKIN:PRLNGD/RPTD CONT W/LIQ
CAN CAUSE FREEZING OF SKIN TISSUES, DEFAT, & DERM. INGEST: SINGLE
DOSE TOX IS LOW TO MOD. IF VOMIT OCCURS LIQ CAN BE ASPIRATED INTO
LUNGS, WHICH CAN CAUSE CHEM PNEUM & SYSTEMIC EFTS. HUMAN
PYSCHOTROPIC,(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. IF BRTHG HAS STOPPED, ADMINISTER
ARTF RESP. SEEK MED ATTN. EYES: FLUSH FOR @ LST 15 MIN W/CLEAR
WATER. IF IRRIT PERSISTS, SEEK MED ATTN. SKIN: WASH W/SOAP & WATER.
FOR FROS TBITE, SEEK IMMED MED ATTN. INGEST: DO NOT INDUCE VOMIT!
GIVE 2 GLASSES OF WATER & IMMED SEEK MED ATTN. NOTE: ADRENALIN &
OTHER SIMILAR CARDIAC STIMULANTS SHOULD NOT BE USED TO TREAT EFTS
(ING 2)

Flash Point Method:TCC
Flash Point:NONE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY RUPTURE WITH FORCE AT
TEMPERATURES ABOVE 120F. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
CHLORIDES, FLUORIDES AND PHOSGENE .

Spill Release Procedures:EVACUATE AREA. VENTILATE AREA AND AVOID
BREATHING VAPORS. VAPOR CONCENTRATION WILL BE HIGHEST ALONG FLOOR
AND IN LOW LYING AREAS. PICK UP LIQUID ON SUITABLE ABSORBENT AND
STORE IN SEALED CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AEROSOL CANS IN COOL PLACE OUT OF
DIRECT SUNLIGHT. KEEP THIS AND ALL CHEMICALS OUT OF REACH OF
CHILDREN. THIS PRODUCT FOR INDUST USE ONLY.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURFACES. HEAT &/OR UV
RADIATION MAY CAUSE FORMATION OF CHLORIDES, FLUORIDES AND PHOSGENE
.

Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR MASK.
Ventilation:DO NOT USE IN CLOSED SPACE. VENTILATION REQUIRED.
Protective Gloves:SOLVENT RESISTANT GLOVES AS (ING 3)
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: GI, & CNS EFTS POSS. CHLOROFLUOROCARBON MATLS HAVE
PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY
BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY EXPOSED TO CFC'S .

HCC:G3
Boiling Pt:B.P. Text:-41F,-41C
Vapor Density:3
Spec Gravity:1.194
pH:7-8
Evaporation Rate & Reference:>1(H*2O=1)
Solubility in Water:0
Appearance and Odor:CLEAR WATER-WHITE LIQUID WITH LOW ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
REACTIVE ALKALI METALS, STRONG ACIDS AND BASES.
Stability Condition to Avoid:CONTACT W/OPEN FLAME, HEAT.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE,
CARBON DIOXIDE, AND CARBON MONOXIDE. CHLORIDES, FLUORIDES .

Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF BY A LICENSED
RECLAIMER OR INCINERATION FACILITY. CONSULT LOCAL, STATE, AND
FEDERAL DISPOSAL AUTHORITIES FOR APPROVED PROCEDURES. DO NOT
INCINERATE OR DESTROY CANS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.